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许峰, 应玲, 汤福隆. 反相高效液相色谱法半制备分离[T(4-MOP)PS4]卟啉的研究[J]. 分析测试技术与仪器, 1994, (1): 34-39.
引用本文: 许峰, 应玲, 汤福隆. 反相高效液相色谱法半制备分离[T(4-MOP)PS4]卟啉的研究[J]. 分析测试技术与仪器, 1994, (1): 34-39.
shu
Xu Feng, Ying Ling, Tang Fulong. Semi-Preparative Class Separation of 5, 10, 15, 20-Tetra( 4-Methoxxyl-3-Sulfophenyl) Porphine by Reversed Phase HPLC[J]. Analysis and Testing Technology and Instruments, 1994, (1): 34-39.
Citation: Xu Feng, Ying Ling, Tang Fulong. Semi-Preparative Class Separation of 5, 10, 15, 20-Tetra( 4-Methoxxyl-3-Sulfophenyl) Porphine by Reversed Phase HPLC[J]. Analysis and Testing Technology and Instruments, 1994, (1): 34-39.
shu

反相高效液相色谱法半制备分离T(4-MOP)PS4卟啉的研究

Semi-Preparative Class Separation of 5, 10, 15, 20-Tetra( 4-Methoxxyl-3-Sulfophenyl) Porphine by Reversed Phase HPLC

    摘要
  • 摘要: 本文研究了新水溶性5,10,15,20-四(4-甲氧基-3-磺酸苯基)卟啉T(4-MOP)PS4的反相高效液相色谱(HPLC)分离条件。采用Shimpack PREP-ODS半制备色谱柱,用含有10mmol/L四乙基碘化铵的乙腈-水(体积比25:75)为流动相,流速18mL/min,于418nm波长下检测。T(4-MOP)PS4与合成中生成的杂质组分完全分离。经此制备的卟啉纯度高,已成功地应用于自来水样中微量钴、锌、铜离子的HPLC测定中。

     

    Abstract: The semi-preparative high performance liquid chromatographic condition of the title compound, a new water soluble prophrin T(4-MOP)PS4, has been established. Using a Shimpack PREP-ODScolumn (14μm, 20mmi.d×250mm) as the Stationary phase and the solution of acetonitrile-water (25:75, V/V) containing 10mmol/L tetraethylammonium iodide as the mobile phase, flow rate 18mL/min, T (4-MOP) PS4 was completely separated from impurities and detected at 418nm. The received.T(4-MOP)PS4 solution has good purity and has been successfully applied to the HPLC determination of trace cobalt(Ⅱ), zinc(Ⅱ) and copper(Ⅱ)in the tap water sample.

     

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